When you use a PS5 controller on Steam, the tiny button under the PS icon lets you take screenshots. In case you didn't know, cuz I didn't until I did it by
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Amazon.com: Oussirro Wireless Controller for Xbox 360, 2.4GHZ Game Controller Gamepad Remote for PC Windows 7,8,10 with Receiver Adapter, No Audio Jack(Black) : Video Games
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